Supramolecular chirality transfer to large random aggregates of porphyrins.

نویسندگان

  • Ilaria Occhiuto
  • Giovanna De Luca
  • Valentina Villari
  • Andrea Romeo
  • Norberto Micali
  • Robert F Pasternack
  • Luigi Monsù Scolaro
چکیده

Chirality is rapidly induced in a fractal aggregate of the porphyrin t-CuPagg by addition of α-helical poly-glutamate. These results demonstrate a facile transfer of chirality via noncovalent interactions to preformed supramolecular assemblies grown in the absence of a chiral template.

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عنوان ژورنال:
  • Chemical communications

دوره 47 21  شماره 

صفحات  -

تاریخ انتشار 2011